棒-板电极下缩比气隙辉光放电相似性的仿真研究

建立了棒-板电极下氩气直流放电的流体模型,利用有限元法对几何位形相似的两个气隙放电过程进行了数值求解.两放电气隙外加电压相同,气隙线性尺寸的比值为10:1,气压分别为1 Torr和10 Torr.仿真得到了两相似气隙的放电的伏安特性曲线以及放电物理量(如电位、电场、电子密度、离子密度、电子温度等)的空间分布.根据气体放电相似性的基本结论,检验了气隙对应物理量之间的数值关系.结果表明:两相似气隙的放电类型为正常辉光放电,对应放电物理量之间存在相似性理论指出的比例关系,且在相同幅值的直流电压作用下,气隙放电的工作点相同.这将为利用气体放电相似性来外推相似气隙的放电特性提供一定的理论依据.     

B$lt;sub$gt;$lt;i$gt;n$lt;/i$gt;$lt;/sub$gt;Y($lt;i$gt;n$lt;/i$gt;=1–11)团簇的结构和电子性质

利用密度泛函理论TPSSh方法对B采用6-311+G(d), 对Y采用Lanl2dz相对论有效势基组, 研究了B_nY (n=1–11)团簇的平均结合能、二阶能量差分、最高分子占据轨道和最低空轨道之间的能级间隙、极化率和第一静态超极化率等物理化学性质. 结果表明, 随着尺寸的增大, B_nY (n=1–11)团簇的最低能量结构从平面逐步演变为立体结构. 随硼原子数n的增加, 团簇的平均结合能表明了较好的热力学稳定性, 有利于Y掺杂B团簇形成较大的块体材料.二阶能量差分表明基态B₃Y, B₅Y和B₇Y团簇较相邻团簇稳定. 能隙表明了基态B₃Y, B₅Y, B₇Y和B₉Y的化学稳定性较高. 综合说明B_nY (n=1–11)硼团簇中, 基态B₃Y, B₅Y和B₇Y具有较好的稳定性. 极化率表明基态B_nY团簇的电子结构随B原子的增加趋于紧凑, 第一静态超极化率表明基态B₅Y, B₄Y, B₃Y和B₆Y平面结构的团簇具有明显的非线性光学性质, 为寻找性能优异的非线性光学材料提供了一定的参考. 关键词： 密度泛函TPSSh方法 nY (n=1–')" href="#">B_nY (n=1– 11)团簇 几何结构 电子性质     

基于相关法的哈特曼图像网格自动划分方法

在哈特曼波前测量过程中,需要对哈特曼图像进行网格划分用于计算波前斜率。传统的网格划分方法通过观察哈特曼图像手动调整网格位置和网格间距。该方法不但需要人工干预,还给波前实时测量带来困难。为实现哈特曼图像网格划分的自动化,研究了基于相关法的哈特曼图像网格自动划分方法。该方法首先对哈特曼图像进行自相关求取网格行列数以及网格间距,然后利用该网格建立相应的模拟光斑图像,最后对模拟光斑图像和哈特曼图像进行互相关求取网格最佳位置。该方法无需人工干预,耗时短,实现了网格实时自动划分。     

Ka波段8路径向波导空间功率分配(合成)器

通过理论研究以及高频仿真相结合的方法分析设计了一款新型Ka波段8路径向波导空间功率分配(合成)器。研发的新结构输入输出段为标准矩形波导结构,代替了传统功率分配(合成)器输入输出段的同轴结构,这种新型全金属结构更加简单紧凑,更易于加工。仿真结果表明:功率分配(合成)器工作带宽达到了34%(12GHz),基本覆盖整个Ka波段;全频带内反射系数S11低于-20dB,各支路的相位差均小于5°。通过在同轴波导渐变段引入切比雪夫渐变结构,在减小了器件尺寸的同时,在整个频带内的网络S参数也不错。这款新型Ka波段8路径向波导功率分配(合成)器将应用于前级固态功率放大器,推动回旋行波管项目研发。     

Q波段回旋行波管宽带高平均功率输出窗设计与热分析

利用场匹配理论建立传输级联矩阵的方法对多层窗片结构输出窗进行研究,通过大量的数值计算给出Q波段回旋行波管一种新型中间风冷结构输出窗的参数,然后通过数值计算和HFSS仿真验证,该新型输出窗在46~50GHz范围内,S11反射系数小于-20dB。在此基础上进一步对该输出窗进行热分析,热分析表明:新型输出窗窗片中心与边缘温差与传统输出窗相比大幅下降,热应力大大减小,提高了输出窗的功率容量。回旋行波管工作在TE01模式时,新型输出窗获得的最大饱和功率容量达到90kW,与传统输出窗相比,功率容量提高了21.8kW。     

二元Ni-Al合金极端条件下的弹性和热力学性能：全电子准谐波近似 cited: 1)

通过在原子尺度上建模来研究Al、NiAl和Ni₃Al合金在极端高温和高压下的点阵常数、弹性常数、弹性模量、泊松比和弹性各向异性因子等性质．计算得到的弹性常数均满足相应的力学稳定条件．由于NiAl和Ni₃Al具有较高的B=G值,在0～30 GPa内都属于延展性材料．通过包含电子热运动对体系吉布斯自由能贡献的全电子准谐近似方法,得到了高温高压下Al、NiAl和Ni₃Al合金的热膨胀系数、体积模量、热容和熵等．计算值与已有的实验值和理论值符合较好     

The synthesis and photolysis mechanisms of 8‐nitroquinoline‐based photolabile caging groups for carboxylic acid

Photolabile protecting groups have been extensively studied and applied for protection of small biological molecules, which make it convenient to detect the biological processes of the caged compounds. In this study, a series of 8‐nitroquinoline‐based photolabile caging groups for carboxylic acid were synthesized with improved photolysis efficiency. Among them, 6‐bromo‐8‐nitro‐1, 2‐dihydroquinolinyl chromophore was proven the best derivative on account of its longest absorption wavelength (345 nm), highest caging ability, and quantum yield (Φ = 0.003). Moreover, density functional theory calculations were performed in order to study the photolysis mechanisms. Theoretical calculations revealed that the reaction was kinetically inert under general mild condition with the high barrier height of 34.3 kcal/mol at carbonyl migration step, while under the photolysis condition, because of the large energy gap (64.5 kcal/mol) between S₀ and S₁ states, the reaction should be accessible in the triplet ground state (T₁) through successive excitation of S₀ → S₁ states, subsequent intersystem crossing of S₁ → T₁ states, and finally returned to the stable S₀ state for product via potential energy surface crossing between T₁ and S₀ states. Copyright © 2014 John Wiley & Sons, Ltd.     

Coherence and Entanglement in Spinor Bose-Einstein Condensate

We propose a scheme to generate and detect quantum coherence and quantum entanglement in a spin-1 Bose-Einstein condensate with the help of spin squeezing parameter and quantum Fisher information. It is shown that quantum coherence and quantum entanglement are independent of the Rabi frequency and the better entanglement can be achieved by increasing the number of atoms.     

Pose estimation for UAV aerial refueling with serious turbulences based on extended Kalman filter

In recent years, many pose estimation algorithms were developed, and have been successfully applied to solve unmanned aerial vehicle (UAV) aerial refueling pose estimation problems. This paper mainly focuses on solving this problem under serious turbulences circumstance. The extended Kalman filter is a set of mathematical equations to estimate the state of a process, which is able to support estimations of past, present, and even future states. In reference to previous papers and some simulations, we build up the noise models of refueling boom and atmospheric turbulence. Then, an extend Kalman filter is adopted to solve the pose estimation problem in UAV aerial refueling with serious turbulences. The experimental results demonstrate the feasibility and effectiveness of our proposed approach.     

A novel multi-directional multi-scroll chaotic system and its CCII+ circuit implementation

This paper proposes a generalized formula of multi-directional multi-scroll chaotic system. Based on the generalized formula, by adding the nonlinear functions, and controlling the parameters of system, multi-directional multi-scroll chaotic attractors with different order system can be generated. According to this method, the correctness of generalized formula is verified. Then, basic dynamic characteristics of the system including the fractal, equilibrium points, Poincaré section, Lyapunov exponent spectrum and bifurcation diagram are analyzed. Finally, a nine-dimensional chaotic circuit based on CCII₊ devices is designed, which verified the feasibility of the generalized formula and multi-directional multi-scroll chaotic circuit with CCII₊ devices.